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Modern engine oils, such as the current SG classification for gasoline engines, contain a large fraction of additives, many of which are detrimental to fluoroelastomers. The primary functions of oil-additive packages are to protect metal parts, avoid deposits in the engine, minimize oil degradation, and adjust fluid viscosity. Little attention has been paid to avoiding damage to rubber seals. Instead, elastomer producers have been expected to provide new, higher-performing products at no increased cost to auto manufacturers. Among the additives with moieties that may attack fluoroelastomers at high temperature are detergents (phenolates), dispersants (succinimides, alkylphenol amines), and antioxidants (amines, sulfides, hindered phenols).⁴ Many of these components are multifunctional, containing phenol or amine groups that can dehydrofluorinate and crosslink VDF-containing fluoroelastomers, leading to loss of elongation and eventual embrittlement. However, the rate and extent of reactions with seals are affected by many factors, including whether air is present in the system. When oil is exposed to air at high temperature, additives may undergo considerable changes. For example, a significant fraction of amines may be oxidized to amides, which have little effect on fluoroelastomers.⁵

Case study 1: Volkswagen

Start the engine and check for oil leaks.

Oil leak: the most frequent failure of the oil seal

Spark plugs play a crucial role in the combustion process of an internal combustion engine. These small but powerful components are responsible for igniting the air-fuel mixture in the engine's cylinders, ultimately powering the vehicle.

What are Oil Seals and how do they work?

Standard 3760/3761

If you are looking for the highest temperature resistant oil seals, Perfluoelastomer can go up to 600°F. If you are more concerned for low temperature, Chloroprene can go all the way down to 40°F, which is why it is used most commonly for refrigeration. And if FDA applications or medical devices are your primary concern, Butyl , the all petroleum compound, will be your best choice. As you can see, when choosing the right material to work with, you must analyze several other key components to help choose the right one. 

Polyacrylate Oil Seals - Mostly selected for automotive and transmission uses, polyacrylate seals are able to withstand fuel, oil, ozone, sunlight and weather when used. With cars exposed to all these different fluids and elements, they are the perfect choice. However, they should not be used in low temperatures, as their flexibility weakens when cold.